Plant Extract
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D-Galactal 21193-75-9 with purity >99% Low price in stock
- Molecular Formula: C6H10O4
- Molecular Weight: 146.143
- Appearance/Colour: White powder
- Vapor Pressure: 1.77E-05mmHg at 25°C
- Melting Point: 99-102 °C
- Refractive Index: -22 ° (C=1.2, MeOH)
- Boiling Point: 325.5 °C at 760 mmHg
- PKA: 12.79±0.60(Predicted)
- Flash Point: 150.7 °C
- PSA： 69.92000
- Density: 1.414 g/cm3
- LogP: -1.38700
D-Galactal(Cas 21193-75-9) Usage
|
Purification Methods |
Recrystallise D-galactal from EtOAc, EtOH or EtOAc/MeOH. [Overend et al. J Chem Soc 675 1950, Wood & Fletcher J Am Chem Soc 79 3234 1957, Distler & Jourdian J Biol Chem 248 6772 1973, Beilstein 17 III/IV 2332.] |
InChI:InChI=1/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6-/m1/s1
21193-75-9 Relevant articles
DIASTEREOSELECTIVE SYNTHESIS OF BRANCHED 2-DEOXY SUGARS VIA RADICAL C-C BOND FORMATION REACTIONS
Giese, Bernd,Groeninger, Kay
, p. 2743 - 2746 (1984)
From glycals 1 and 6, 2-deoxy sugars can...
2-nitroglycal and efficient synthesis method thereof
-
Paragraph 0056-0058, (2021/08/06)
The invention discloses an efficient syn...
Me3SI-promoted chemoselective deacetylation: a general and mild protocol
Gurawa, Aakanksha,Kashyap, Sudhir,Kumar, Manoj
, p. 19310 - 19315 (2021/06/03)
A Me3SI-mediated simple and efficient pr...
Ir(I)-Catalyzed C?H Glycosylation for Synthesis of 2-Indolyl-C-Deoxyglycosides
Yu, Changyue,Liu, Yichu,Xie, Xiong,Hu, Shulei,Zhang, Shurui,Zeng, Mingjie,Zhang, Dan,Wang, Jiang,Liu, Hong
supporting information, p. 4926 - 4931 (2021/09/09)
The construction of 2-deoxy-C-glycosides...
Total Synthesis of Tri-, Hexa- and Heptasaccharidic Substructures of the O-Polysaccharide of Providencia rustigianii O34
Ahadi, Somayeh,Awan, Shahid I.,Werz, Daniel B.
supporting information, (2020/05/04)
A general and efficient strategy for syn...
21193-75-9 Process route
-
-
14125-64-5
(2R,3R)-3-hydroxy-2-(hydroxymethyl)-2H-pyran-4(3H)-one
-
-
13265-84-4,21193-75-9,25312-13-4,26566-29-0,29485-85-6,63949-52-0,81275-42-5,130931-62-3,145375-16-2
1,2-didehydrodideoxyallose
-
-
13265-84-4
D-glucal
Conditions
| Conditions | Yield |
|---|---|
|
With
sodium tetrahydroborate; cerium(III) chloride heptahydrate;
In
methanol;
at 0 ℃;
for 1h;
optical yield given as %de;
diastereoselective reaction;
Inert atmosphere;
|
-
-
4098-06-0
triacetyl-D-galactal
-
-
21193-75-9
D-galactal
Conditions
| Conditions | Yield |
|---|---|
|
With
sodium methylate;
In
methanol;
|
100%
|
|
With
lipase A from Aspergillus niger;
In
aq. phosphate buffer; acetonitrile;
at 25 ℃;
for 1h;
pH=7;
Enzymatic reaction;
|
99%
|
|
With
ammonia;
In
methanol;
at 20 ℃;
for 5h;
|
97%
|
|
With
methanol; potassium carbonate;
|
97.6%
|
|
With
methanol; potassium permanganate; trimethylsulphonium iodide;
at 25 ℃;
under 760.051 Torr;
chemoselective reaction;
|
96%
|
|
With
methanol; sodium methylate;
at 20 ℃;
Inert atmosphere;
|
95%
|
|
triacetyl-D-galactal;
With
sodium methylate;
In
methanol;
at 25 ℃;
for 2h;
pH=> 11;
Inert atmosphere;
|
95%
|
|
With
triethylamine;
In
methanol; water;
at 20 ℃;
for 24h;
|
92%
|
|
With
water; triethylamine;
In
methanol;
at 20 ℃;
|
92%
|
|
With
methanol; sodium;
|
89%
|
|
With
sodium methylate;
In
methanol;
for 72h;
|
87%
|
|
With
ammonia;
In
methanol;
for 15h;
Yield given;
Ambient temperature;
|
|
|
With
sodium methylate;
In
methanol;
|
|
|
With
sodium;
In
methanol;
for 12h;
|
|
|
With
anion-exchange resin (Amberlite IRN-78, OH- form);
In
methanol;
for 15h;
Ambient temperature;
|
|
|
With
ammonia;
In
methanol;
|
|
|
With
sodium methylate;
In
methanol;
at 20 ℃;
for 24h;
|
0.73 g
|
|
With
sodium methylate;
In
methanol;
|
|
|
With
methanol; sodium methylate;
at 20 ℃;
for 3h;
|
|
|
With
sodium methylate;
In
methanol;
at 20 ℃;
|
|
|
With
sodium methylate;
In
methanol;
at 20 ℃;
for 1.5h;
|
|
|
With
sodium methylate;
In
methanol;
|
|
|
With
methanol; sodium methylate;
at 20 ℃;
for 2h;
|
|
|
With
sodium methylate;
In
methanol;
at 20 ℃;
|
|
|
With
sodium methylate;
In
methanol;
at 20 ℃;
for 24h;
Inert atmosphere;
|
|
|
With
methanol; sodium methylate;
at 0 - 20 ℃;
for 1h;
Inert atmosphere;
|
|
|
With
methanol; sodium;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
|
|
|
With
potassium carbonate;
In
methanol;
at 20 ℃;
for 3h;
|
|
|
With
sodium methylate;
In
methanol;
at 0 ℃;
for 3h;
|
|
|
With
methanol; sodium methylate;
at 20 ℃;
for 3h;
Inert atmosphere;
|
|
|
With
methanol; sodium methylate;
at 20 ℃;
|
2.7 g
|
|
With
sodium methylate;
In
methanol;
Inert atmosphere;
|
|
|
With
methanol; sodium methylate;
at 20 ℃;
for 1.5h;
Inert atmosphere;
|
|
|
With
sodium methylate;
In
methanol;
at 0 ℃;
for 3h;
|
21193-75-9 Upstream products
-
2873-29-2
D-glucal triacetate
-
4098-06-0
triacetyl-D-galactal
-
3068-32-4
1-bromo-1-deoxy-2,3,4,6-tetra-O-acetyl-a-D-galactopyranoside
-
4163-60-4
β-D-galactose peracetate
21193-75-9 Downstream products
-
108866-73-5
O 1 -Benzoyl-α-D-talopyranose
-
3971-45-7
methyl 2-deoxy-α-D-galactopyranoside
-
138406-76-5
Acetic acid (2S,3R,4S,5R)-5-acetoxy-4-((2S,4R,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester
-
80040-79-5
3,4,6-tri-O-benzyl-D-galactal
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