Others
Purity 99% Min 2-Hexyn-1-ol 764-60-3 Spot Supply with Safe Transportation
- Molecular Formula: C6H10 O
- Molecular Weight: 98.1448
- Appearance/Colour: COLORLESS TO YELLOW LIQUID
- Vapor Pressure: 2.52mmHg at 25°C
- Melting Point: -52.5°C
- Refractive Index: n20/D 1.4536(lit.)
- Boiling Point: 66-67 ºC (10 mmHg)，140.5 °C at 760 mmHg
- PKA: 13.00±0.10(Predicted)
- Flash Point: 154 ºF
- PSA： 20.23000
- Density: 0.893
- LogP: 0.78220
2-Hexyn-1-ol(Cas 764-60-3) Usage
InChI:InChI=1/C6H10O/c1-2-3-4-5-6-7/h7H,2-3,6H2,1H3
764-60-3 Relevant articles
Synthesis of α,β-unsaturated epoxy ketones utilizing a bifunctional sulfonium/phosphonium ylide
Eskandari, Roozbeh,Hess, Jeremy P.,Tochtrop, Gregory P.
supporting information, p. 7136 - 7139 (2021/07/28)
Herein, a new protocol for rapid synthes...
Enantioselective Rhodium-Catalyzed Dimerization of ω-Allenyl Carboxylic Acids: Straightforward Synthesis of C2-Symmetric Macrodiolides
Steib, Philip,Breit, Bernhard
supporting information, p. 6572 - 6576 (2018/05/08)
Herein, we report on the first enantiose...
Gold(III)-Catalyzed Regioselective Oxidation/Cycloisomerization of Diynes: An Approach to Fused Furan Derivatives
Li, Jian,Xing, Hong-Wen,Yang, Fang,Chen, Zi-Sheng,Ji, Kegong
supporting information, p. 4622 - 4626 (2018/08/07)
The first gold(III)-catalyzed regioselec...
Sodium Phenoxide Mediated Hydroxymethylation of Alkynylsilanes with N-[(Trimethylsiloxy)methyl]phthalimide
Asano, Narumi,Sasaki, Keita,Chataigner, Isabelle,Shigeno, Masanori,Kondo, Yoshinori
supporting information, p. 6926 - 6930 (2017/12/26)
The hydroxymethylation of alkynylsilanes...
764-60-3 Process route
-
-
18937-79-6
methyl 2-hexynoate
-
-
764-60-3
hex-2-yn-1-ol
Conditions
| Conditions | Yield |
|---|---|
|
With
diisobutylaluminium hydride;
In
diethyl ether;
at -78 - 20 ℃;
for 3h;
|
95%
|
|
With
diisobutylaluminium hydride;
In
diethyl ether;
at -78 ℃;
for 2h;
|
89%
|
-
-
106-94-5
propyl bromide
-
-
107-19-7
propargyl alcohol
-
-
764-60-3
hex-2-yn-1-ol
Conditions
| Conditions | Yield |
|---|---|
|
With
Iron(III) nitrate nonahydrate; ammonia; lithium;
In
tetrahydrofuran;
at -78 - 20 ℃;
|
99%
|
|
With
lithium amide;
In
tetrahydrofuran; ammonia;
-30 deg C then reflux, 2 h.;
|
84%
|
|
With
lithium amide;
1.) liq. NH3, -30 deg C, 1 h, 2.) THF, reflux, 8 h;
|
82.7%
|
|
propargyl alcohol;
With
N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 - -30 ℃;
Inert atmosphere;
propyl bromide;
In
tetrahydrofuran; hexane;
at -30 - 20 ℃;
Inert atmosphere;
|
57%
|
|
With
lithium; ferric nitrate;
Yield given. Multistep reaction;
1.) liquid ammonia, dry THF, 1 h, 2.) dry THF, 2 h;
|
|
|
With
ammonia; lithium;
Yield given. Multistep reaction;
1.) 1,5 h; 2.) ether, 1 h;
|
|
|
With
lithium amide;
|
|
|
propargyl alcohol;
With
N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 - -30 ℃;
Inert atmosphere;
propyl bromide;
In
tetrahydrofuran; hexane;
at -30 - 20 ℃;
Inert atmosphere;
|
764-60-3 Upstream products
-
13280-07-4
4-chlorobut-2-yn-1-ol
-
925-90-6
ethylmagnesium bromide
-
6089-04-9
3-(tetrahydropyran-2'-yloxy)propyne
-
106-94-5
propyl bromide
764-60-3 Downstream products
-
18495-25-5
1-bromohex-2-yne
-
928-94-9
(Z)-2-hexen-1-ol
-
928-95-0
(E)-2-Hexen-1-ol
-
51453-66-8
1-chloro-3-hex-2-ynyloxy-propan-2-ol
WANT TO
PURCHASE